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Atomistry » Vanadium » Chemical Properties » Oxalo-vanadates | ||
Atomistry » Vanadium » Chemical Properties » Oxalo-vanadates » |
Oxalo-vanadates
These compounds are obtained in large yellow prisms (side by side with red polyvanadates) by the action of vanadium pentoxide on boiling solutions of alkali oxalates, or by the action of normal alkali vanadates on acid oxalates. They have the general formula 3R•2O.V2O5.4C2O3.xH2O or
![]() 2R•2.V2O5.2C2O3.2MoO3.xH2O (RNH4 or K.) and 3R•2.V2O5.2C2O3.6MoO3.xH2O. (R = NH4, Na, K or ½Ba.) These are most probably derivatives of the oxalo-vanadates in which co-ordinative oxygen atoms have undergone substitution by (MoO4)'' groups. Hence they are alternatively represented as ![]() ![]() respectively. |
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